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NOBIN is an organic molecule used for asymmetric catalysis, related to BINOL and other analogs. It is prepared by oxidative cross coupling of 2-naphthol and 2-naphthylamine, and can be resolved by camphorsulfonic acid.
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The methods for the preparation of enantiopure NOBIN included asymmetric cross-coupling reaction of 2-naphthol and 2-naphthylamine, optical resolution of its racemic form and transformation from ...
NOBIN is a binaphthyl analogue that can be used as a chiral ligand in asymmetric catalysis. This article reviews the methods for preparing enantiopure NOBIN and its derivatives, and their applications in various reactions, such as aldol, Diels-Alder, transfer hydrogenation and Suzuki coupling.