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tert-butyl hydroperoxide is potentially dangerous, but explosions are rare. [3]A solution of tert-butyl hydroperoxide and water with a concentration of greater than 90% is forbidden to be shipped according to US Department of Transportation Hazardous Materials Table 49 CFR 172.101.. In some sources it also has an NFPA 704 rating of 4 for health, 4 for flammability, 4 for reactivity and is a ...
1.3.2 Thermal Hazards Compared with most other hydroperoxides, T-Hydro TBHP has high thermal stability. The material is stable at temperatures below approximately 38°C (100°F), and unadulterated
Metabolic activation of peroxides and hydroperoxides to free radicals is associated with the tumor promoting activity of these compounds. tert-Butyl hydroperoxide (t-BOOH) metabolism has been extensively studied as a model of peroxide biotransformation.
SAFETY DATA SHEET Creation Date 12-Sep-2014 Revision Date 24-Dec-2021 Revision Number 8 1. Identification Product Name tert-Butyl hydroperoxide, 70% solution in water Cat No. : AC180340000; AC180340025; AC180340050; AC180340100;
tert-Butyl hydroperoxide solution 70 wt. % in H2O; CAS Number: 75-91-2; Synonyms: TBHP,1,1-Dimethylethyl hydroperoxide,2-Hydroperoxy-2-methylpropane; Linear Formula: (CH3)3COOH at Sigma-Aldrich
IUPAC Standard InChIKey: CIHOLLKRGTVIJN-UHFFFAOYSA-N Copy CAS Registry Number: 75-91-2 Chemical structure: This structure is also available as a 2d Mol file; Other names: Hydroperoxide, 1,1-dimethylethyl; Cadox TBH; Perbutyl H; 2-Hydroperoxy-2-methylpropane; 1,1-Dimethylethyl hydroperoxide; tert-C4H9OOH; tert-Butyl hydrogen peroxide; Hydroperoxide, tert-butyl; Hydroperoxyde de butyle tertiaire ...
Recent Literature. Various aromatic, aliphatic and conjugated alcohols were transformed into the corresponding carboxylic acids and ketones in good yields with aq 70% t-BuOOH in the presence of catalytic amounts of bismuth(III) oxide.This method possesses does not involve cumbersome work-up, exhibits chemoselectivity and proceeds under ambient conditions.
tert-Butyl hydroperoxide (CAS 75-91-2) information, including chemical properties, structure, melting point, boiling point, density, formula, molecular weight, uses ...
3.2.3.4 Oxidant and Epoxidation Solvent. t-Butyl hydroperoxide (TBHP) is used as the oxidant for nearly all titanium-catalyzed asymmetric epoxidations.Exceptions are for allyl alcohol and methallyl alcohol, where cumyl hydroperoxide is used to advantage for the epoxidation. 4 Cumyl hydroperoxide can be used for other epoxidations and is reported to result in slightly faster reaction rates than ...
TBHP has emerged as a greener and economically viable oxygen source, radical initiator and precursor of t-BuO⋅ and t-BuOO⋅ radicals.It is extensively utilized as a reagent for the synthesis of epoxides, ketones, secondary alcohols, heterocyclic rings like benzofurans, isoquinoline and many more.